She is shown to have major dislike for him while he simply ignores her because of her arrogant and mean nature.
During his third mission, Kanade discovered that her breasts are actually silicone through "Absolute Choices", after she declined his request. Embarrassed by the revelation, Ayame quickly brought Kanade into the locker room to hide from the crowd. She then questioned him as to how he knew about her secret. Thinking he meant giving herself to him, she starts undressing as he quickly stops her and says just to say she likes him which will in turn save her secret. She eventually says that she "likes" him while being embarrassed.
After this, she is shown to still be hostile while he is annoyed with her but keeps her secret.
They don't get along as Ayame tends to mock her because not only is she a part of the "reject five" but also a "Flat chested woman." Furano fights right back and because of this they have an ongoing rivalry.
Furano fights right back and because of this they have an ongoing rivalry. After the contest however, Ayame has a big debt with Furano as she lied about Reikadou's chest being real. When asked by Kanade, she murmurs that she understands her in a way, because she too would like bigger breasts.